Salvete!
One good way of learning how to catalogue is by checking out individual MARC records, particularly if you know their origin to be trusted, like LOC records. This record is from my hometown catalogue for an encyclopaedia. The MARC tutorial that Marty suggested is another good idea. Just be aware that some fields are local in nature, so you don't need to repeat them in your record. For example, the 49$a field here just shows who holds the set.
Cheers,
Brooke @ Hinsdale MA
LDR:
01047nam 22002657a 450
005:
20060118003400.0
008:
050706s2006 ilu bf 001 0deng
010:
$a 2005016631
020:
$a 0716601060
035:
$a 579856
035:
$a ocm60826453
040:
$a DLC $c DLC $d GC0 $d VUE
049:
$a RCSC $b APLM BETH EGRN GUIL RCSC SNLK
050:
00 $a AE5 $b .W55 2006
082:
00 $a 031 $2 22
245:
04 $a The World Book encyclopedia.
250:
$a 2006 ed.
260:
$a Chicago : $b World Book, Inc., $c c2006.
300:
$a 22 v. : $b ill. (some col.), col. maps ; $c 26 cm.
504:
$a Includes bibliographical references and index.
520:
0 $a v. 1. A -- v. 2. B -- v. 3. C-Ch -- v. 4. Ci-Cz -- v. 5. D -- v. 6. E -- v. 7. F -- v. 8. G -- v. 9. H -- v. 10. I -- v. 11. J-K -- v. 12. L-- v. 13. M -- v. 14. N-O -- v. 15. P -- v. 16. Q-R -- v. 17. S-Sn -- v. 18. So-Sz -- v. 19. T -- v. 20. U-V -- v. 21. W-X-Y-Z -- v. 22. Research Guide - Index.
650:
0 $a Encyclopedias and dictionaries.
710:
2 $a World Book, Inc.
994:
$a 02 $b VUE
995:
$a 579856